Heat oven to 200 degrees. Mix flour, cornstarch, salt, baking powder, and baking soda in a large bowl.
In another bowl, whisk yolks with oil; add milk, buttermilk, vanilla and whisk until combined. Set aside.
Beat egg white in a small bowl with an electric mixer to almost soft peaks. Sprinkle in sugar and continue beating until white and glossy.
Pour wet ingredients into dry ingredients and mix until just mixed. Add egg white to batter in dollops. Fold in with a spatula until just incorporated.
Add batter to preheated waffle iron following manufacturer’s instructions and cook until crisp and brown. Set waffle directly on rack in oven to keep it warm and crisp, at least 5 minutes and up to 20 minutes.
Notes: do not overfill waffle iron—trying to cook too much batter keeps them from becoming crisp. *For more vanilla flavor, use double strength vanilla extract.